Reaction of Isoquinolinium Ylides and Isoquinolinium Imines with Ketenethioacetal Derivatives
نویسندگان
چکیده
منابع مشابه
Formation of diverse polycyclic spirooxindoles via three-component reaction of isoquinolinium salts, isatins and malononitrile
The triethylamine promoted three-component reaction of N-(4-nitrobenzyl), N-ethoxycarbonylmethylisoquinolinium bromide, isatins and malononitrile in ethanol afforded spiro[indoline-3,2'-pyrrolo[2,1-a]isoquinolines] in good yields and with high diastereoselectivity. The similar reaction of N-cyanomethylisoquinolinium chloride mainly gave complex indolo[2″,3″:2',3']pyrrolo[3',4':4,5]pyrrolo[2,1-a...
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The title compound, C(13)H(11)NO(4)·H(2)O, is a monohydrate of a betaine exhibiting a positively charged N-substituted isoquino-line group and a deprotonated carboxyl group. In the crystal, mol-ecules are connected via short O-H⋯O hydrogen bonds between protonated and deprotonated carboxyl groups into chains of either R or S enanti-omers along [001]. These chains are additionally connected by h...
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We have developed a highly efficient procedure for carrying out the catalytic enantioselective (3+2) cycloaddition between enals and stable azomethine ylides such as isoquinolinium and phthalizinium methylides. Under the optimized reaction conditions highly substituted chiral pyrroloisoquinolines and pyrrolophthalazines have been obtained in high yields and excellent diastereo- and enantioselec...
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The title compound, C(17)H(18)NO(+)·I(-), is an adduct resulting from an intra-molecular Diels-Alder reaction of methallyl chloride with 3,4-dihydro-1-furylisoquinoline. The cation comprises a fused penta-cyclic system containing three five-membered rings (dihydro-pyrrole, dihydro-furan and tetra-hydro-furan) and two six-membered rings (tetra-hydro-pyridine and benzene). The five-membered rings...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1977
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.97.12_1316